The couple received a call about Africa's most feared snake, the black mamba.

Simon and Siouxsie receive a terrified call from a woman who spotted a large brown snake in her kitchen. After a tense search, Simon removes the oven to come face to face with an enormous black mamba.

After getting a call from a family who spotted a snake behind their kitchen cupboards, Simon and Siouxsie rush over there to find a lethal spitting cobra has made itself at home

After getting a call from a family who spotted a snake behind their kitchen cupboards, Simon and Siouxsie rush over there to find a lethal spitting cobra has made itself at home

After getting a call from a family who spotted a snake behind their kitchen cupboards, Simon and Siouxsie rush over there to find a lethal spitting cobra has made itself at home

The duo receives a call from a man who is certain he has spotted two large black mambas in his chicken coop. The situation turns dangerous when the snake spits its venom in Siouxsie's face as they try to capture it.

Snake catcher Simon Keys and his girlfriend, Siouxsie Gillett, receive a call when a huge snake is spotted in the swimming pool of a country club. When they arrive, they spot the snake curled up in the shallow end, and it's one of the biggest black mambas they have ever seen. Simon and Siouxsie jump into the pool to catch it, but it is so large and powerful that they struggle to pin it down.

Snake catcher Simon Keys and his girlfriend, Siouxsie Gillett, receive an unusual call from snake catchers in Cape Town, South Africa. Wildfires have erupted around the city, forcing the wildlife to take refuge in people's homes and gardens. Panicked calls increase as deadly snakes seek shelter from the fire. Simon and Siouxsie will be faced with snakes they have never caught before.