The New Adventures of Superman

Luthor Strikes Again (1x28)

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Lex Luthor kidnaps Jimmy Olsen in a plot to destroy Superman. When Superman comes to the rescue, Lex and his henchmen attack him with Kryptonite ray guns. Fortunately, Superman falls into a vat of lead-based paint. Protected from the Kryptonite rays, Superman saves Jimmy and captures Lex Luthor.