Naruto Shippuden
Jiraiya Ninja Scrolls: The Tale of Naruto the Hero - Leaving the Village (20x13)
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Sasuke leaves the village in order to obtain power from Orochimaru. Naruto and his friends learn that Sasuke is in danger and decide to go after him. To keep this a secret, only Naruto and Shikamaru set out on this mission, but on the way the duo are accosted by masked ANBU shinobi!