Highlander: The Series

Avenging Angel (1x20)

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When fatal stabbing fails to kill him, Alfred Cahill becomes convinced that he has been chosen by a higher power to wage a crusade against 'perversion', and cuts a bloody path through Paris, murdering prostitutes and pimps, and endangering an old friend of Tessa's who has become a call girl. MacLeod tries to explain Immortality to Cahill, but he can't get through to him, and finally is forced to take his head.